Bingham Model or Bingham Equation
A simple rheological model that relates shear stress and shear rate and quantifies
yield stress and high-shear viscosity.
Brookfield Viscosity
A simple viscosity value, usually reported in centipoise (cP), obtained with a Brookfield Viscometer, usually
fitted with a dip-in spindle but may also be fitted with some specialist accessories such as Cone/Plate, Helipath stand and
T-Bar spindles or a concentric cylinder measuring system such as a Small Sample Adaptor or Ultra-Low Accessory.
More..
Carreau Model or Carreau Equation A relative of the Cross Model that is often fitted to viscosity vs shear rate profiles.
Casson Model or Casson Equation
A commonly used rheological model that quantifies yield stress and high shear
viscosity, typically used for inks and molten chocolate.
Complex
Modulus
The
overall resistance to deformation of a material, regardless of whether that deformation is recoverable (elastic) or non-recoverable
(viscous). Symbol G*.
Complex
Viscosity
Complex Modulus divided by Angular Frequency.
Compliance
The ratio strain/stress. Symbol J
Creep Test
A rheological test method where a constant
low stress is applied to a material and it's resulting deformation and flow is monitored over the period of the test.
Cross
Model or Cross Equation
Crossover
Frequency
In an oscillatory (or dynamic) frequency sweep, the frequency at which the elastic and viscous moduli cross, usually
marking the transition from the terminal (viscous) region to the rubbery plateau (elastic) region).
Dilatancy
Shear thickening – non-Newtonian behaviour where viscosity
increases with increasing shear rate.
Elastic Modulus
The contribution of elastic (solid-like)
behaviour to the complex modulus. Symbol G".
Herschel
Bulkley Model
A rheological model that combines
the Power law model with a yield stress variable.
Instantaneous
Elastic Compliance
In a creep test, the
compliance achieved instantaneously upon the impostion of stress.
Kinematic
Viscosity
The
dynamic viscosity divided by density. Typically reported in Stokes or centiStokes.
Loss
Angle
Another name
for Phase Angle
Loss
Modulus
Another name for Viscous Modulus. Symbol G".
Loss Tangent
Another name
for Tan Delta
Newtonian
Fluid
A fluid which exhibits a viscosity
that is independent of the current shear conditions.
Non-Newtonian
Fluid
A fluid which exhiits a viscosity
that is dependent upon the shear conditions.
Ostwald (or Ostwald de Waele) Model
Same as Power law Model
Phase Angle
The
phase difference between the stress and strain in an oscillatory test. A measure of the presence and extent
of elastic behaviour in a fluid. Symbol δ.
Power
Law Model
A
useful rheological model that describes the relationship between viscosity or shear stress and shear rate over the range
of shear rates where shear thinning occurs in a Non-Newtonian fluid. Quantifies overall viscosity range and degree of
deviation from Newtonian behaviour. More about the Power Law Model..
Pseudoplastic Same as shear-thinning
Relaxation Time
A time constant describing the rate of
relaxation of stresses in a material (eg a viscoelastic fluid) that has been deformed to a defined strain.
Rheopexy
Time dependent viscosity increase at constant shear rate –
often known as anti-thixotropy.
Shear Rate
The rate of change of shear
stress. The velocity gradient perpendicular to the direction of shear flow (dv/dx). Units 1/s
or s-1
Shear Stress
The
shear force per unit area. Symbol s or t. Units of Pascals (Pa)
Shear
Strain
A unit-less
quantity, the relative displacement of the faces of a sheared body (for example a layer of fluid) divided by the distance
between them.
Shear Thinning
A non-Newtonian fluid which exhibits higher viscosities
at lower shear rates and vice-versa.
Storage
Modulus
Another
name for Elastic Modulus. Symbol G'.
Tan Delta
The tangent of the phase angle – the ratio of viscous modulus
to elastic modulus and a useful quantifier of the presence and extent of elasticity in a fluid.
Thixotropy
Time
dependent viscosity change at constant shear rate. A thixotropic fluid is a shear-thinning fluid
that takes a finite time to reach an equilibrium viscosity following a step change in the applied shear rate.
Vane Spindle
A four or six bladed paddle measuring system that can be employed instead of cones, plates, cylinders or spindles on a
rheometer or viscometer. The vane is often used to eliminate slippage and sample damage upon loading.
Viscoelasticity
The
phenomenon of exhibiting both elastic (solid-like or energy storing) and viscous (liquid-like or energy dissipating) properties.
See here
Viscosity
The
resistance of a fluid to flow. In shear deformation viscosity is the ratio of applied shear stress to resulting
shear rate. Typcally reported in units of Poise (P) and centipoise (cP) or Pascal seconds (Pa.s) or milliPascal
seconds (mPa.s). Symbol, typically h.
Viscous
Modulus
The
contribution of viscous (liquid-like) behaviour to the Complex Modulus. Symbol G".
Wall slip A phenomenon seen in dispersions where
a low-viscosity slip layer forms at a smooth surface due to localised depletion (wall depletion) of the dispersed phase.
Wall slip leads to poor viscosity data at low shear rates but can be eliminated by employing crosshatched (or serrated), roughened
or grooved measuring systems. See here for more.
Yield
Stress In
a shear-thinning product, the minimum stress that must be applied to initiate significant (i.e. more than creeping) flow
and a significant drop in viscosity.
Zero-shear Viscosity
The viscosity at the limit of low shear rate. In essence, the
viscosity a product will ultimately attain when at rest and undisturbed.