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Rheology Glossary

A Glossary Of Rheological Terms
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Bingham Model or Bingham Equation
A simple rheological model that relates shear stress and shear rate and quantifies yield stress and high-shear viscosity. 
 
Brookfield Viscosity
A simple viscosity value obtained with a Brookfield Viscometer, usually fitted with a dip-in spindle but may also be fitted with some specialist accessories such as Cone/Plate,  Helipath stand and  T-Bar spindles or a concentric cylinder measuring system such as a Small Sample Adaptor or Ultra-Low Accessory.  More..
 
Carreau Model or Carreau Equation
A relative of the Cross Model that is often fitted to viscosity vs shear rate profiles.
 
Casson Model or Casson Equation
A commonly used rheological model that quantifies yield stress and high shear viscosity, typically used for inks and molten chocolate.
 
Complex Modulus
The overall resistance to deformation of a material, regardless of whether that deformation is recoverable (elastic) or non-recoverable (viscous).
 
Complex Viscosity
Complex Modulus divided by Angular Frequency
 
Compliance
The ratio strain/stress.  Symbol J
 
Creep Test
A rheological test method where a constant low stress is applied to a material and it's resulting deformation and flow is monitored over the period of the test.
 
Cross Model or Cross Equation
A rheological model commonly fitted to viscosity vs shear rate profiles. 
More about the Cross Model..
 
Crossover Frequency
In an oscillatory (or dynamic) frequency sweep, the frequency at which the elastic and viscous moduli cross, usually marking the transition from the terminal (viscous) region to the rubbery plateau (elastic) regio). 
 
Dilatancy
Shear thickening – non-Newtonian behaviour where viscosity increases with increasing shear rate.
 
Elastic Modulus
The contribution of elastic (solid-like) behaviour to the complex modulus
 
Herschel Bulkley Model
A rheological model that combines the Power law model with a yield stress variable.
 
Instantaneous Elastic Compliance
In a creep test, the compliance achieved instantaneously upon the impostion of stress.
 
Kinematic Viscosity
The dynamic viscosity divided by density
 
Loss Angle
Another name for Phase Angle
 
Loss Modulus
Another name for Viscous Modulus
 
Loss Tangent
Another name for Tan Delta
 
Newtonian Fluid
A fluid which exhibits a viscosity that is independent of the current shear conditions.
 
Non-Newtonian Fluid
A fluid which exhiits a viscosity that is dependent upon the shear conditions.
 
Ostwald (or Ostwald de Waele) Model
Same as Power law Model
 
Phase Angle
The phase difference between the stress and strain in an oscillatory test.  A measure of the presence and extent of elastic behaviour in a fluid. Symbol δ
 
Power Law Model
A useful rheological model that describes the relationship between viscosity or shear stress and shear rate over the range of shear rates where shear thinning occurs in a Non-Newtonian fluid. Quantifies overall viscosity range and degree of deviation from Newtonian behaviour.  More about the Power Law Model..
 
Pseudoplastic
Same as shear-thinning
 
Relaxation Time
A time constant describing the rate of relaxation of stresses in a material (eg a viscoelastic fluid) that has been deformed to a defined strain. 
 
Rheopexy
Time dependent viscosity increase at constant shear rate – often known as anti-thixotropy.
 
Shear Rate
The rate of change of shear stress.  The velocity gradient perpendicular to the direction of shear flow (dv/dx).  Units 1/s or s-1
 
Shear Stress
The shear force per unit area
 
Shear Strain
A unit-less quantity, the relative displacement of the faces of a sheared body (for example a layer of fluid) divided by the distance between them.
 
Shear Thinning
A non-Newtonian fluid which exhibits higher viscosities at lower shear rates and vice-versa.
 
Slippage
A phenomenon seen in dispersions where a low-viscosity slip layer forms at a smooth surface due to localised depletion (wall depletion) of the dispersed phase.
 
Storage Modulus
Another name for Elastic Modulus
 
Tan Delta
The tangent of the phase angle – the ratio of viscous modulus to elastic modulus and a useful quantifier of the presence and extent of elasticity in a fluid.
 
Thixotropy
Time dependent viscosity change at constant shear rate.  A thixotropic fluid is a shear-thinning fluid that takes a finite time (usually seconds to minutes) to reach an equilibrium viscosity following a step change in the applied shear rate.
 
Vane Spindle
A four or six bladed paddle measuring system that can be employed instead of cones, plates, cylinders or spindles on a rheometer or viscometer.  The vane is often used to eliminate slippage and sample damage upon loading.
 
Viscoelasticity
The phenomenon of exhibiting both elastic (solid-like or energy storing) and viscous (liquid-like or energy dissipating) properties
 
Viscosity
The resistance of a fluid to flow
 
Viscous Modulus
The contribution of viscous (liquid-like) behaviour to the Complex Modulus
 
Yield Stress
In a shear-thinning product, the minimum stress that must be applied to initiate significant (i.e. more than creeping) flow and a significant drop in viscosity.
 
Zero-shear Viscosity
The viscosity at the limit of low shear rate. The viscosity a product will ultimately attain when at rest and undisturbed.
 
 

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