Viscosity Profiling
Emulsions, suspensions, solutions and
gels are all examples of non-Newtonian fluids – that is, their viscosity is not a fixed value but is dependent
upon the degree of shear they are exposed to. Most commonly, shear-thinning is observed where viscosity decreases with increasing
shear rate. For such products a single viscosity value can be meaninglessl
exhibit non-Newtonian behavious and gels all exhibit non-Newtonian behaviopur - instead a “flow curve”
of viscosity against shear rate is required, from which the value at a shear rate relevant to the process or product usage
conditions can be read.
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| Viscosity profiles of Newtonian syrup and non-Newtonian mayonnaise. |
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“At-rest” Viscosity
Zero-shear
viscosity, the viscosity of a product when effectively at rest, is a contributor to suspension and emulsion stability and
a sensitive indicator of changes in a product resulting from ageing or changes in the formulation or process.
A highly sensitive air-bearing rheometer such as our AR2000 is a necessity for measurement of zero-shear viscosity.
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| Zero shear viscosity and shear thinning viscosity profiles |
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Rheology Model Fits for Pump-sizing and Process Design
A range of rheological models can be fitted to quantify flow curves and obtain parameters for inputting into process
design and engineering calculations. Models include:
Bingham and Casson Power Law and Herschel Bulkley Sisko Cross and Carreau
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| Power Law model fit for Power Law Index and Consistency parameters. |
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Viscosity / Temperature Relationships
Viscosity typically, but not
always, exhibits an inverse relationship with temperature. A viscosity-temperature profile can be obtained
under defined imposed shear conditions relevant to the process.
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| Viscosity temperature profile comparisons of 3 oils. |
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Thixotropy: Viscosity and Structure Recovery After Shearing.
Following a period
of earlier shearing from, for example, a mixing, filling or coating process, some products will very quickly recover
their viscosity whereas others will go on building viscosity slowly for hours, days or even weeks. A
product that exhibits a long, slow viscosity build to a highly-structured state after shearing is termed thixotropic.
Various methods are available to quantify thixotropic recovery rates. Shown here is a 3-step thixotropy
test for comparing recovery after application of two cosmetic skin products. The sample is subjected to an initial
low-shear conditioning step, then a high-shear structure-breakdown step and finally a recovery step at the original low shear
rate. The proportion of viscosity recovered at the end of the final step can then be easily quantified. The
second sample exhibits a poor recovery compared to the sample in the first graph.
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| This sample exhibits a near-full recovery in step 3 following the high-shear of step 2. |
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| This sample exhibits only a minimal recovery after the high shear of step 2 |
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Viscoelastic Characterisation and Oscillatory Testing
Oscillatory
shear testing is employed to characterise and quantify the presence, rigidity and integrity of internal structure resulting
from, for example, flocculation of dispersed particles or droplets, or cross-linking and entanglement of dissolved polymers.
Typically measured parameters include:
Complex modulus (G*) Elastic (or storage) modulus (G') and
viscous (or loss) modulus (G") Phase angle (δ) and tangent of the phase angle (tan δ).
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| Complex modulus and phase angle provide a simple viscoelastic |
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Oscillation Stress Sweeps
Oscillation stress
and strain sweeps provide easy-to-interpret information about the soft-solid rigidity and yield stress (gel strength) of even
delicately-structured fluids such as fruit juices and thickened drinks, "light-touch" lotions and sedimentation-resistant
suspensions.
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| Oscillation stress sweep reveals soft solid stiffness and strength in two emulsions. |
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Oscillatory Frequency Sweeps
Oscillatory frequency
sweeps allow us to probe and identify the nature of the structuring mechanisms present in a fluid. The sample is exposed
to small-deformation oscillations covering a range of frequencies to assess the structural response to deformations of longer
or shorter timescales. The graphic shows how the technique can differentiate between the "relaxable" structure
found in a polymer solution (where polymers disentangle to dissipate stored stresses) and the more permanent elasticity
found in a flocculated suspension. This technique can prove a useful tool when attempting to match textures and
flow behaviours in thickened systems.
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| Oscillatory frequency sweeps can reveal the nature of the structuring mechanisms. |
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