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A Simple Explanation Of Visco-elastic Parameters

Viscoelastic parameters can be a bit daunting for the rheology newbie so here’s my simplest explanation of the meaning and significance of two useful numbers you can obtain from a simple oscillation test:

Imagine four corners of a graph each represent "ideal" material types. Top left is occupied by stiff solids (such as steel and stone), top right are thick liquids (treacle, heavy oils etc), bottom left are soft solids (jelly, soft rubber) and bottom right are thin liquids (water, solvents).

modulusvsphaseanglecopy.gif

The vertical axis represents resistance to deformation (increasing stiffness or viscosity) while the horizontal axis represents a progression from solid (elastic) behaviour to liquid-like (viscous) behaviour. The rheological parameters complex modulus (G*) and phase angle (δ) respectively quantify these properties, and both can be gained from a simple oscillation test. Structured fluids and soft solids - the viscoelastic materials we see in real life – occupy various positions on this “map”, their location defined by their complex modulus and phase angle.

A typical application for this kind of characterisation is in the assessment of dispersions. A solid suspension undergoing flocculation will show a progression upwards and to the left as the modulus rises and the associating particles form a network that deforms elastically under applied stress. A suspension can then be tested at weekly or monthly intervals with a simple oscillation stress sweep.

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